安兴民, 何大可. 三元配合物的组成和稳定常数的测定[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 1990, (4).DOI:
三元配合物的组成和稳定常数的测定
摘要
用两相滴定法测定了Zr(Ⅳ)
U(Ⅳ)
Pt(Ⅳ)
Pd(Ⅱ)和Ag(Ⅰ)分别在HPMBP—TBP—甲苯体系和HDEHP—TBP—苯体系中形成的三元混
配合物的组成和稳定常数β_。
Abstract
A method of two-phase titraton was applied to determinate the compositions and stability con stants of the mixed complexes of Zr(Ⅳ)
U(Ⅳ)
Pt(Ⅳ)
Pd(Ⅲ)
Ag(Ⅰ) with Di—2—ethyl hexyl phosphoric acid (HDEHP)or an acid ligand 1—phenyl—3—Methyl—4 —benzoylpyrazolone—5 (HPMBP) and a neutral ligand tributyl phosphate (TBP).