单纯, 耿超英, 俞建群, et al. 双-β-二酮缩甘氨酸合双铜(Ⅱ)配合物的合成及非等温热分解反应动力学[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 1998, (3).
单纯, 耿超英, 俞建群, et al. 双-β-二酮缩甘氨酸合双铜(Ⅱ)配合物的合成及非等温热分解反应动力学[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 1998, (3).DOI：
The paper reports the synthetic procedure and character of copper(Ⅱ) binuclear coordination compound of schiff base derived from 1
4 bis (1′ phenyl 3′ methyl 5′pyrazolone 4′)butanedione and glycine.The non isothermal kinetics of thermal decomposition of the complex has been studied from the TG-DTG Curves by means of the Achar and Coats Redfern methods
the most probable kinetic equation can be expressed as d α/ d t=3/2Ae -E/RT (1-α) 4/3 [1/(1-α) 1/3 -1] -1 . The mathematics expression of the kinetic compensation effect is found to be ln A=0.2698E+0.1942.
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