牛园园, 陆江银, 齐艳杰. α-己烯/α-辛烯/α-十二烯三元聚合物减阻率研究[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2012, 29(2): 127-131.DOI：
Aα-hexylene/α-dodecene/α-octylene copolymer was synthesized by solution polymerization with TiCl4 / Al(i-Bu)3 Composite catalyst andα-olefin monomers.Effects of the polymerization conditions on drag reduction rate were investigated.The experimental resuslts showed that the drag reduction rate could up to 54.11%under the optimum condition of catalyst TiCU 0.06g
co-catalyst Al(i-Bu)30.2 mL
V(α-dodecene):V(α-octylene):V(α-hexylene)=3:2:1(the total volume of monomer is 30mL)
dissolvent(nhexane) 10 mL and initial reaction temperature-10℃.The IR、XRD and ~1HNMR results showed the DRA was a-olefin polymer with low crystallinity.
京公网安备11010802024621