王恩生, 傅明瑨, 安兴民. 水溶性卟啉铑螯合物的合成和光助还原水放氢的研究[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 1993, (2).DOI：
水溶性卟啉铑螯合物的合成和光助还原水放氢的研究
摘要
本文合成了5-(4-硝基)苯基-10
15
20-三(4-磺酸钠)苯基卟啉和5
10
15
20-四[4-(4′-磺酸钠)苯亚胺基]苯基卟啉两种水溶性配体及相应的Rh的螯合物
进行了元素分析
电子光谱
IR
~1HNMR和TGA表征。并以光敏剂-TiCl3-K_2PtCl6组成复合体系
在450W汞灯和自然光照下试验了放H2性能
结果表明
所合成的四种化合物均有光敏性。
Abstract
In this paper
two water-soluble ligands: 5-(4-nitrophenyl)
10
15
20-tri (4'-sodium sulfonatophenyl) porphyrin
5
10
15
20-tetra (4-(4'-sodium sulfonatophenylimino) phenylporphyrin and their Rh (Ⅲ) Chelates have been synthesized and characterized by elemental analysis
electronic spectra
IR
~1H-NMR and TGA. The function of Hydrogen generation have. been tested. The results showed that all the formed compounds have the capacity for Hydrogen generation when they were irradiated by mercury-vapor lamp or natural light.
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