新疆大学物理科学与技术学院
纸质出版:2017
移动端阅览
[1]崔秀花,穆保霞,王振,等.高振动激发态CsH(v)与CO_2碰撞弛豫过程的实验研究[J].新疆大学学报(自然科学版),2017,34(01):49-53.
[1]崔秀花,穆保霞,王振,等.高振动激发态CsH(v)与CO_2碰撞弛豫过程的实验研究[J].新疆大学学报(自然科学版),2017,34(01):49-53. DOI: 10.13568/j.cnki.651094.2017.01.010.
DOI:10.13568/j.cnki.651094.2017.01.010.
在Cs-H2系统和CO2的混合系统中
采用简并受激超拉曼(DSHR)泵浦技术
研究了CsH分子的高位振动激发态与CO2的碰撞弛豫过程
测量了CsH(v=15-23)与CO2之间的各振动弛豫系数
实验表明v=22时
碰撞弛豫速率系数达到最大值.
The collisional relaxation processes between the highly vibrationally excited Cs H(v=15-23) and CO2 have been studied by using a degenerate stimulated hypor raman pumping technique. With Cs-H2 and CO_2mixture
the vibrational levels of Cs H(v=0) were generated in the reaction of Cs(7P) and(H2). Rate constants kv(Cs H-CO2) for collisional relaxations were measured accurately when Cs H level v=15 increases to v=23. For v=22
the rate coefficients is maximum.
Huang X C,Schwenke D W,Tashkun S A,et al.An isotopic-independent highly accurate potential energy surface for CO2isotopologues and an initial12C16O2infrared line list[J].J Chem Phys,2012,36:124311-1/17.
Jongma R T,Wodtke A M.Fast multiquantum vibrational relaxation of highly vibrationally excited O2[J].J Chem Phys,1999,111:10957-10963.
Mc Caffery A J,Pritchard M,Turner J F C,et al.Quantum state-resolved energy redistribution in gas ensembles containing highly excited N2[J].J Chem Phys,2011,134:044317-1/12.
穆保霞,崔秀花,郭国生,等.KH(X1+,V=14-21)高位振动态与CO2碰撞速率系数的测定[J].新疆大学学报,2014,31(3):312-315.
Yuan L W,Du J,Mullin A S.Energy-dependent dynamics of large-?E collisions:highly vibrationally excited azulene(E=20390 and 38 580 cm-1)with CO2[J].J Chem Phys,2008,129(1):014303-1/11.
Wall M C,Stewart B A,Mullin A S.State-resolved collisional relaxation of highly vibrationally excited pyridine by CO2:Influence of a permanent dipole moment[J].J Phys Chem A,1998,108:6185-6196.
Mack J A,Mikulecky K,Wodtke A M.Resonant vibration–vibration energy transfer between highly vibrationally excited O2(X3Σ-g,v=15–26)and CO2,N2O,N2,and O3[J].J Chem Phys,1996,105:4105-4116.
Jongma R T,Wodtke A M.Fast multiquantum vibrational relaxation of highly vibrationally excited O2[J].J Chem Phys,1999,111:10957-10963.
Cui X H,Mu B X,Shen Y F,et al.Vibrational relaxation and vibration-rotation energy transfer between highly vibrationally excited KH(X1Σ+,v=14–21)and CO2[J].J Quant Spectrosc Radiat Transfer,2012,113:2081-2087.
Vadla C,Horvatic V,Niemax K.Radiative transport and collisional transfer of excitation energy in Cs vapors mixed with Ar or He[J].Spectrochimica Acta B,2003,58:1235-1277.
Mu B X,Cui X H,Shen Y F,et al.State-resolved collisional relaxation of highly vibrationally excited Cs H by CO2[J].Spectrochimica Acta Part A,2015,148:299-310.
Stwalley W C,Zemke W T,Yang S C.Spectroscopy and structure of the alkali hydride diatomic molecules and their ions[J].J Phys Chem Ref Date,1991,20(1):153-187.
Cui X H,Mu B X,Shen Y F,et al.Excitation transfer for K2in high-lying states by N2[J].Chin Phys Lett,2010,27(7):073401-1/4.
0
浏览量
35
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621
