新疆大学地质与矿业工程学院新疆中亚造山带大陆动力学与成矿预测自治区重点实验室
纸质出版:2021
移动端阅览
[1]李顺达,陈川,夏芳,等.山东七宝山Au–Cu矿床流体演化及成矿机理研究[J].新疆大学学报(自然科学版)(中英文),2021,38(03):321-333.
[1]李顺达,陈川,夏芳,等.山东七宝山Au–Cu矿床流体演化及成矿机理研究[J].新疆大学学报(自然科学版)(中英文),2021,38(03):321-333. DOI: 10.13568/j.cnki.651094.651316.2020.05.12.0001.
DOI:10.13568/j.cnki.651094.651316.2020.05.12.0001.
矿床位于山东半岛SW部.角砾状及脉状矿化发育在石英闪长玢岩与辉石闪长岩中.成矿阶段划分为:I镜铁矿–自然金–石英阶段
II黄铁矿–黄铜矿–石英阶段
III贫硫化物–石英–方解石阶段.I阶段石英中发育富气相与含子矿物包裹体
盐度分别为0.7~5.4 wt.%与40.6~51.3 wt.%
均一温度352~479℃;II阶段石英中发育富液相、富气相及含子矿物包裹体
盐度分别为0.7~2.1 wt.%
4.2~18.4 wt.%
34.5~40.2 wt.%
均一温度233~342℃;III阶段仅发育富液相包裹体
盐度5.0~9.9 wt.%
均一温度135~246℃.石英样品氢氧碳同位素分析结果指示成矿流体初始为岩浆水
随后大气降水混入
并与含碳地层发生水–岩交换.黄铁矿及黄铜矿硫同位素指示成矿物质源于石英闪长玢岩及部分其他围岩.矿床属于典型的中温岩浆热液矿床.
The Qibaoshan Au–Cu deposit is located in the southwestern Shandong Peninsula. Mineralization occurs in breccia and veins within pyroxene diorite and quartz diorite porphyry. Three paragenetic stages are identified in Qibaoshan Au–Cu deposit: stage I specularite–gold–quartz
stage II pyrite–chalcopyrite–quartz
and stage III poor sulfide–quartz–calcite. Stage I fluids in vapor–rich and daughter mineral bearing inclusions have salinities of 0.7 ~ 5.4 wt.% and 40.6 ~ 51.3 wt.% homogenization temperature of 352 ~ 479 ℃; Stage II fluids in liquid–rich
vapor–rich and daughter mineral bearing inclusions have salinities of 0.7 ~ 2.1 wt.%
4.2 ~ 18.4 wt.%
34.5 ~ 40.2 wt.%
respectively
homogenization temperature of 233 ~ 342 ℃; Stage 3 fluids in liquid–rich inclusions have salinities of 5.0 ~ 9.9 wt.% and homogenization temperature of 135 ~ 246 ℃. Oxygen
hydrogen
and carbon isotopic data of quartz indicate that the ore-forming fluids were of magmatic origin
then mixed with meteoric water
and had a water–rock reaction with carbon–bearing strata. Sulfur isotopic data for chalcopyrite and pyrite reveal that the ore–forming materials were mainly derived from quartz diorite porphyry
with minor contributions from wall rocks Qibaoshan is a mesothermal magmatic hydrothermal deposit.
ROEDDER E.Fluid inclusions[J].Reviews in Mineralogy,1984,12:644.
LI X F,WANG C,HUA R,et al.Fluid origin and structural enhancement during mineralization of the Jinshan orogenic gold deposit,South China[J].Mineralium Deposita,2010,45:583-597.
CALAGAEI AA.Fluid inclusion studies in quartz veinlets in the porphyry copper deposit at Sungun,East-Azarbaidjan,Iran[J].Journal of Asian Earth Sciences,2004,23:179-189.
侯辉,马海杰,汪立今,等.新疆加曼特金矿与斑岩型金矿的对比研究[J].新疆大学学报(自然科学版),2015,32(1):17-20.HOU H,MA H J,WANG L J,et al.Comparative study of porphyry-type gold deposit and Jiamante gold deposit in Xinjiang[J].Journal of Xinjiang University (Natural Science Edition),2015,32(1):17-20.(in Chinese)
IZAWA E,URASHIMA Y,IBARAKI K,et al.The Hishikari gold deposit:high-grade epithermal veins in Quaternary volcanics of southern Kyushu,Japan[J].Journal of Geochemical Exploration,1990,36:1-56.
HITZMAN M W,ORESKES N,EINAUDI M T.Geological characteristics and tectonic setting of proterozoic iron oxide (Cu-U-Au-REE) deposits[J].Precambrian Research,1992,58:241-287.
SILLITOE R.Iron oxide-copper-gold deposits:an Andean view[J].Mineralium Deposita,2003,38:787-812.
KESKER S E,APPOLD M S,MARTINI A M,et al.Na-Cl-Br systematics of mineralizing brines in Mississippi Valley-type deposits[J].Geology,1995,23:641-644.
王郁.山东七宝山金矿床地质特征及成因探讨[J].地质论评,1991,37(4):329-337.WANG Y.Geological characteristics and origin of Qibaoshan gold deposit in Shandong province[J].Geological Review,1991,37(4):329-337.(in Chinese)
张连营,程敏清.山东五莲七宝山金铜矿床地球化学特征及成因分析[J].地质找矿论丛,1996,1:18-24.ZHANG L Y,CHENG M Q.Geochemical characteristics of Qibaoshan Au-Cu deposit Shandong province and it’s genesis[J].Contributions to Geology and Mineral Resources Research,1996,1:18-24.(in Chinese)
徐文刚,范宏瑞,胡芳芳,等.山东七宝山隐爆角砾岩型Cu-Au矿床流体包裹体及成矿流体演化特征[J].岩石学报,2015,31(4):1015-1030.XU W G,FAN H R,HU F F,et al.Fluid inclusions of the Qibaoshan Cu-Au deposit,Shandong Province,China[J].Acta Petrologica Sinica,2015,31(4):1015-1030.(in Chinese)
王永,范宏瑞,胡芳芳,等.山东五莲七宝山Cu-Au矿床成矿流体特征及成矿作用[J].岩石学报,2008,24(9):2029-2036.WANG Y,FAN H R,HU F F,et al.Ore-forming fluids and metallogenesis of the Qibaoshan Cu-Au deposit in the Wulian County,Shandong Province,China[J].Acta Petrologica Sinica,2008,24(9):2029-2036.(in Chinese)
孙思,李永刚,张小允,等.山东七宝山隐爆角砾岩型金铜矿床含矿蚀变斑岩石英颗粒中高温高盐度沸腾包裹体的发现及其意义[J].岩石学报,2010,26(11):3319-3326.SUN S,LI Y G,ZHANG X Y,et al.Boiling fluid inclusions of high temperature and high salinity in the quartz grains in altered porphyry from the Au-Cu-bearing cryptoexplosion breccia pipe at Qibaoshan,Shandong Province and their significance[J].Acta Petrologica Sinica,2010,26(11):3319-3326.(in Chinese)
张淼.山东省五莲县七宝山铁氧化物-金-铜(IOCG)型矿床地质特征及矿床成因[D].长春:吉林大学,2016.ZHANG M.Geological characterisitics and genesis of Qibaoshan Iron Oxide-Copper-Gold (IOCG) deposit,Wulian County,Shandong Province[D].Changchun:Jilin University,2016.(in Chinese)
周建波,郑永飞,吴元保.苏鲁造山带西北缘五莲花岗岩中锆石U-Pb年龄及其地质意义[J].科学通报,2002,22:1745-1750.ZHOU J B,ZHENG Y F,WU Y B.Zircon U-Pb age and geological significance of the Wulian granite in northwest Sulu orogenic belt[J].Chinese Science Bulletin,2002,22:1745-1750.(in Chinese)
ZHENG Y F,CHEN R X,ZHAO Z F.Chemical geodynamics of continental subduction-zone metamorphism:Insights from studies of the Chinese Continental Scientific Drilling (CCSD) core samples[J].Tectonophysics,2009,475:327-358.
CHEN J F,XIE Z,LI H M.U-Pb zircon ages for a collision-related K-rich complex at Shidao in the Sulu ultrahigh pressure terrane,China[J].Geochemical Journal,2003,37:35-46.
郭敬辉,陈福坤,张晓曼,等.苏鲁超高压带北部中生代岩浆侵入活动与同碰撞-碰撞后构造过程:锆石U-Pb年代学[J].岩石学报,2005,21(4):1281-1301.GUO J H,CHEN F K,ZHANG X M,et al.Evolution of syn-to post-collisional magmatism from north Sulu UHP belt,eastern China:Zircon U-Pb geochronology[J].Acta Petrologica Sinica,2005,21(4):1281-1301.(in Chinese)
YANG J H,CHUNG S L,WILDE S A,et al.Petrogenesis of post-orogenic syenites in the Sulu Orogenic Belt,East China:geochronological,geochemical and Nd-Sr isotopic evidence[J].Chemical Geology,2005,214:99-125.
YANG K F,FAN H R,SANTOSH M,et al.Reactivation of the Archean lower crust:Implications for zircon geochronology,elemental and Sr-Nd-Hf isotopic geochemistry of late Mesozoic granitoids from northwestern Jiaodong Terrane,the North China Craton[J].Lithos,2012,146/147:112-127.
YANG Q Y,SANTOSH M,SHEN J F,et al.Juvenile vs.recycled crust in NE China:Zircon U-Pb geochronology,Hf isotope and an integrated model for Mesozoic gold mineralization in the Jiaodong Peninsula[J].Gondwana Research,2014,25:1445-1468.
MA L,JIANG S Y,DAI B Z,et al.Multiple sources for the origin of Late Jurassic Linglong adakitic granite in the Shandong Peninsula,eastern China:Zircon U-Pb geochronological,geochemical and Sr-Nd-Hf isotopic evidence[J].Lithos,2013,162/163(Complete):251-263.
GOSS S C,WILDE S A,WU F,et al.The age,isotopic signature and significance of the youngest Mesozoic granitoids in the Jiaodong Terrane,Shandong Province,North China Craton[J].Lithos,2010,120:309-326.
GUO P,SANTOSH M,LI S.Geodynamics of gold metallogeny in the Shandong Province,NE China:An integrated geological,geophysical and geochemical perspective[J].Gondwana Research,2013,24:1172-1202.
YU G Y,WANG Z G,WANG K Y,et al.The magma evolution sequence and geodynamic setting in the Qibaoshan ore area,Wulian County,Shandong Province,China[J].Geological Journal,2018,54:1238-1253.
BODNAR R J.Revised equation and table for determining the freezing point depression of H2O-Na Cl solutions[J].Geochimica Et Cosmochimica Acta,1993,57:683-684.
BODNAR J R,VITYK M O.Interpretation of microthermometric data for H2O-Na Cl fluid inclusions[C]In:De Vivo,B and Frezzotti,M L,Eds,Fluid Inclusions in Minerals:Methods and Application,Pontignsno-Siena,Virginia Technical Institute,1994,117-130.
FRIEDMAN I.Deuterium content of natural waters and other substances[J].Geochimica Et Cosmochimica Acta,1953,4:89-103.
CLAYTON R N,MAYEDA T K.The use of bromine pentafluoride in the extraction of oxygen from oxides and silicates for isotopic analysis[J].Geochimica et Cosmochimica Acta,1963,27:43-52.
ROBINSON B W,KUSAKABE M.Quantitative preparation of sulfur dioxide,for34S/32S analyses,from sulfides by combustion with cuprous oxide[J].Analytical Chemistry,1975,47:1179-1181.
HOLLISTER L S,BURRUSS R C.Phase equilibria in fluid inclusions from the Khtada Lake metamorphic complex[J].Geochimica Et Cosmochimica Acta,1976,40:163-175.
GOLDSTEIN R H,REYNOLD T J.Systematics of fluid inclusions in diagenetic minerals[M].Canada:SEPM Short Course,1994.
SHEPHERD T J,RANKIN A H,ALDERTON D.A Practical Guide to Fluid Inclusion Studies[M].Glasgow:Blackie and Son,1985.
CLAYTON R N,O’NEIL J R,MAYEDA T K.Oxygen isotope exchange between quartz and water[J].Journal of Geophysical research,1972,77:3057-3067.
RAMBOZ C,PICHAVANT M,WEISBROD A.Fluid immiscibility in natural processes:use and misuse of?uid inclusion data:II.Interpretation of?uid inclusion data in terms of immiscibility[J].Chemical Geology,1982,37:1-27.
DRIESNER T,HEINRICH C A.The system H2O-Na Cl.Part I:correlation formulae for phase relations in temperature-pressurecomposition space from 0 to 1 000℃,0 to 5 000 bar and 0 to 1 X Na Cl[J].Geochimica Et Cosmochimica Acta,2007,71:4880-4901.
SIAHCHESHM K,CALAGARI A A,ABEDINI A.Hydrothermal evolution in the Maher-Abad porphyry Cu-Au deposit,SWBirjand,Eastern Iran:Evidence from fluid inclusions[J].Ore Geology Reviews,2014,58:1-13.
TAYLOR H.The application of oxygen and hydrogen isotope studies to problems of hydrothermal alteration and ore deposition[J].Economic Geology,1974,69:843-883.
LI S D,ZHANG X B,GAO L L.Ore genesis at the Jinchang gold-copper deposit in Heilongjiang Province,northeastern China:evidence from geology,fluid Inclusions,and H-O-S isotopes[J].Minerals,2019,9:99.
SHMULOVICH K I,LANDWEHR D,SIMON K,et al.Stable isotope fractionation between liquid and vapour in water-salt systems up to 600℃[J].Chemical Geology,1999,157:343-354.
TAYLOR B E.Magmatic volatiles:isotopic variations of C,H and S[J].Reviews in Mineralogy,1986,16:185-225.
LI S D,WANG K Y,WANG Y C,et al.Genesis of the Bairendaba Ag-Zn-Pb deposit,Southern Great Xing’an Range,NEChina:a fluid inclusion and stable isotope study[J].Geofluids,2017,11:1-18.
KODERA P,LEXA J,RANKIN A H,et al.Epithermal gold veins in a caldera setting:Banska Hodrusa,Slovakia[J].Mineralium Deposita,2005,39:921-943.
CLAEK I D,FRITZ P.Environmental Isotopes in Hydrogeology[M].New York:Lewis Publishers,1997.
OHMOTO H,RYE R O.Isotopes of sulfur and carbon[M].New York:John Wiley and Sons,1979.
OHMOTO H,GOLDHABER M.Sulphur and carbon isotopes.In:Barnes HL (ed) Geochemistry of hydrothermal ore deposits[M].New York:Wiley,1997.
弓小平,李晓光.西天山阿吾拉勒铁成矿带西段含矿地层地球化学特征及成矿过程分析[J].新疆大学学报(自然科学版),2017,34(3):273-278.GONG X P,LI X G.The analysis of the geochemical characteristics for mineral-bearing formation and metallogenic processes in the Awulale Iron Metallogenic Belt West Tianshan[J].Journal of Xinjiang University (Natural Science Edition),2017,34(3):273-278.(in Chinese)
张博文,展新忠,陈川,等.西天山喇嘛苏外围铜矿床岩石地球化学及成矿背景研究[J].新疆大学学报(自然科学版),2018,35(1):86-95.ZHANG B W,ZHANG X Z,CHEN C,et al.Study on petrogeochemistry and metallogenic background of Lamasuwaiwei copper deposit in Western Tianshan Orogenic[J].Journal of Xinjiang University (Natural Science Edition),2018,35(1):86-95.(in Chinese)
韩秉峻,弓小平,刘祥,等.新疆冰草沟地区铀矿地球化学及成矿特征[J].新疆大学学报(自然科学版),2018,35(4):513-521.HAN B J,GONG X P,LIU X,et al.Geochemical and metallogenic characteristics of uranium deposit in Bingcaogou region,Xinjiang[J].Journal of Xinjiang University (Natural Science Edition),2018,35(4):513-521.(in Chinese)
OHMOTO H.Systematics of sulfur and carbon isotopes in hydrothermal ore deposits[J].Economic Geology,1972,67:551-578.
ZARTMAN R E,DOE B R.Plumbotectonics-the Model[J].Tectonophysics,1981,75:135-162.
LI Q L,CHEN F,YANG J H,et al.Single grain pyrite Rb-Sr dating of the Linglong gold deposit,eastern China[J].Ore Geology Reviews,2008,34:263-270.
HU F F,FAN H R,JIANG X H,et al.Fluid inclusions at different depths in the Sanshandao gold deposit,Jiaodong Peninsula,China[J].Geofluids,2013,13:528-541.
ZHANG L C,LIU T B,SHEN Y C,et al.Structure,isotopes and40Ar/39Ar dating of the Pengjiakuang gold deposit,Mesozoic Jiaolai basin,eastern China[J].International Geology Review,2003,45:691-711.
MAO J W,XIE G Q,ZHANG Z H,et al.Mesozoic large-scale metallogenic pulses in North China and Corresponding geodynamic setting[J].Acta Petrologica Sinica,2005,21:169-188.
MAO J W,PIRINO F,COOK N.Mesozoic metallogeny in East China and corresponding geodynamic settings-An introduction to the special issue[J].Ore Geology Reviews,2011,43:1-7.
0
浏览量
181
下载量
0
CSCD
关联资源
相关文章
相关作者
相关机构
京公网安备11010802024621
