张丽静, 解成喜, 钱秀英, et al. 非离子型微乳液存在下5-Br-PADAP光度法测定微量Co(Ⅱ)的研究[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2000, (3).
张丽静, 解成喜, 钱秀英, et al. 非离子型微乳液存在下5-Br-PADAP光度法测定微量Co(Ⅱ)的研究[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2000, (3).DOI:
非离子型微乳液存在下5-Br-PADAP光度法测定微量Co(Ⅱ)的研究
摘要
研究了在含水量 90 %的非离子型微乳液——乳化剂 op/正丁醇 /正庚烷 /水中
在室温下用 5- Br- PADAP与 Co( )的显色反应进行
分光光度法测定钴
配合物最大吸收波长在 588nm
摩尔吸光系数达 1 .1 3*1 0 5 L· mol-1· cm-1
与相同含水量的乳化剂 OP胶束体系相比
本法测定的灵敏度明显提高 .Co含量 0~ 30μg/ 2 5ml范围符合比耳定律
Abstract
This article studies the chromogenic reaction of cobalt(Ⅱ) with 5 Br PADAP in a nonionic micromemulsion containing appropriate amounts of emulgent:OP
n butanol n hepane and 90% water
under the ambient temperature.The results of the photometric analysis are as follows:the maximum wave length of absorption of the complex is 588nm;the molar absorptivity is 1.13\+*10\+5L·mol\+\{-1\}·cm\+\{-1\}
and when the amount of cobalt(Ⅱ)ranges from 0 to 30 μg/25 mL
it obeys the Beer′s law.Compared with the micelle system with only one kind of emulgent
op
and the same amount of water
the method used here improve the sensiveness dramatically.