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1. 石油天然气精细化工教育部和自治区重点实验室
2. 新疆大学化学化工学院
Published:2011
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[1]崔慧妍,马凤云,刘建超,等.低压下炼钢飞灰对将军庙煤加氢催化液化工艺性能影响研究[J].新疆大学学报(自然科学版),2011,28(04):383-388+376.
崔慧妍, 马凤云, 刘建超, et al. 低压下炼钢飞灰对将军庙煤加氢催化液化工艺性能影响研究[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2011, 28(4): 383-388.
以将军庙煤为研究对象
首先不加催化剂
选用L9(34)正交表
确定了煤样直接液化最适宜的工艺条件.然后
考察飞灰及其在助催化剂硫作用下的液化效果.最后考察NiSO4和CoSO4以浸渍担载和机械混合两种方法分别与飞灰复配后
对煤样液化性能的改进.试验结果表明:(1)将军庙煤具有"四高三低"特点
即高挥发分、较高镜质组分、高硫、高H/C
低惰质组、低灰分、低水分.按照俄罗斯结构-化学指数模型计算
该煤的不饱和度δ=8.72
还原指数B=15.36
适宜于直接液化;(2)在无催化剂条件下
该煤适宜的加氢液化条件为P(H2)=6.5 Mpa
T=420℃
S/C=2:1
其油产率达到61.19%
转化率达到85.00%;(3)当以飞灰为主催化剂
S为助催化剂时
其油产率达到72.10%
转化率达到88.20%.催化效果最好;(4)在飞灰复配催化剂中
担载型飞灰/Ni液化率可达到80.36%
催化活性较高;(5)几种催化剂的催化效果排序:飞灰/S≈担载型飞灰/S/Ni≈担载型飞灰/Ni>飞灰.
The sample is the coal from Jiangjunmiao Xinjiang.At first
its appropriate conditions for direct liquefaction without catalysts were obtained by L9(34);then the influences of steelmaking flue dust and with the help of sulphur on the liquefaction performances were investigated;finally
the steelmaking flue dusts were composited with NiSO4 and CoSO4 respectively by methods of infusion and mechanical mixing
then
the influences of modified steelmaking flue dusts on the liquefaction performances were researched.The results are that
the sample has a characteristic of "four high and three low"
i.e.high volatile
vitrinite
sulphur and H/C as well as low inertinite
ash and moisture;according to the structure-chemical exponent calculating model in Russia
its unsaturation degree δ is 8.72
deoxidation exponent B is15.36
so the sample is suitable for liquefaction;without catalysts
on the appropriate liquefied conditions of P(H2) = 6.5MPa
T = 420 C and S / C(ratio of solvent to coal) = 2:1
its oil yield and conversion were 61% and 85%;as a catalyst of steelmaking flue dust and sulphur
its oil yield and conversion reached 72.10% and 88.20%;the catalyst of steelmaking flue dust/Ni has better action
its liquefaction yield was 80.36%;the action order of those catalysts is steelmaking flue dust /S ≈ steelmaking flue dust/S /Ni ≈ steelmaking flue dust /Ni>steelmaking flue dust.
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马凤云,周剑林,周岐雄,等.铁基催化剂的硫化及其对煤直接液化的影响[J].煤炭转化,2010,33(3):49-51.
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