ZnO柱撑有机皂石对聚乳酸结晶性能的影响

孙金陆; 甄卫军

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ZnO柱撑有机皂石对聚乳酸结晶性能的影响

更新时间：2026-01-21

- ZnO柱撑有机皂石对聚乳酸结晶性能的影响
- Journal of Xinjiang University (Natural Science Edition in Chinese and English) Vol. 30, Issue 4, Pages: 384-389(2013)
- 作者机构：
  
  石油天然气精细化工教育部(自治区)重点实验室,新疆大学化学与化工学院
- 作者简介：
- 基金信息：
- DOI：
  CLC： O631.3
- Published：2013
- 稿件说明：
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[1]孙金陆,甄卫军.ZnO柱撑有机皂石对聚乳酸结晶性能的影响[J].新疆大学学报(自然科学版),2013,30(04):384-389+505.

孙金陆, 甄卫军. ZnO柱撑有机皂石对聚乳酸结晶性能的影响[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2013, 30(4): 384-389.
[1]孙金陆,甄卫军.ZnO柱撑有机皂石对聚乳酸结晶性能的影响[J].新疆大学学报(自然科学版),2013,30(04):384-389+505. DOI：

孙金陆, 甄卫军. ZnO柱撑有机皂石对聚乳酸结晶性能的影响[J]. Journal of Xinjiang University (Natural Science Edition in Chinese and English), 2013, 30(4): 384-389. DOI：

摘要

采用微波水解法制备ZnO柱撑皂石

通过十六烷基三甲基溴化铵(CTAB)有机改性制备ZnO柱撑有机皂石

并以其为助剂通过熔融插层法制备了聚乳酸(PLA)/ZnO柱撑有机皂石纳米复合材料.X射线衍射(XRD)及红外光谱分析(FT-IR)表明皂石层状结构被剥离形成了纳米级皂石层片且有机改性效果良好.采用Avrami法对PLA/ZnO柱撑有机皂石纳米复合材料的非等温结晶动力学进行了分析

结果表明:ZnO柱撑有机皂石缩短了PLA的半结晶周期(t1/2)

提高了PLA的结晶速率

PLA晶体以二维或三维的方式增长.

Abstract

ZnO pillared saponite was prepared through microwave hydrolysis method. Moreover

ZnO pillared organic saponite was prepared with cetyltrimethylammonium bromide(CTAB)

then poly lactic acid(PLA)/ZnO pillared organic saponite nanocomposites were prepared by melting intercalation processing. The structures of ZnO pillared organic saponite were characterized by X-ray Difraction(XRD) and FT-IR

which suggested that the layer structures of saponite has been exfoliated into nanoscale layer and the efect of organic modification was well. Non-isothermal crystallization kinetics of PLA was studied by Avrami method

which showed that the addition of ZnO pillared organic saponit shortened the half-crystallization time(t1/2) and improved the crystallization rate of PLA

the crystal of PLA developed with two or three-dimension.

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references

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