一锅法制备铋基催化剂在乙炔氢氯化反应中催化性能的研究（英文）

漆维霞; 王璐; 王丰; 王吉德

doi:10.13568/j.cnki.651094.2017.02.001

您当前的位置：

首页 >

文章列表页 >

一锅法制备铋基催化剂在乙炔氢氯化反应中催化性能的研究（英文）

更新时间：2026-01-21

- 一锅法制备铋基催化剂在乙炔氢氯化反应中催化性能的研究（英文）
- Journal of Xinjiang University (Natural Science Edition in Chinese and English) Vol. 34, Issue 2, Pages: 127-132(2017)
- 作者机构：
  
  新疆大学石油天然气精细化工教育部和自治区重点实验室化学化工学院
- 作者简介：
- 基金信息：
- DOI：10.13568/j.cnki.651094.2017.02.001
  CLC： O643.36
- Published：2017
- 稿件说明：
移动端阅览
[1]漆维霞,王璐,王丰,等.一锅法制备铋基催化剂在乙炔氢氯化反应中催化性能的研究（英文）[J].新疆大学学报(自然科学版),2017,34(02):127-132.
[1]漆维霞,王璐,王丰,等.一锅法制备铋基催化剂在乙炔氢氯化反应中催化性能的研究（英文）[J].新疆大学学报(自然科学版),2017,34(02):127-132. DOI： 10.13568/j.cnki.651094.2017.02.001.

DOI：10.13568/j.cnki.651094.2017.02.001.

摘要

本文采用一锅法(PM)和等体积浸渍法(IM)制备了铋基催化剂并考察了PM的制备条件对催化剂的影响.使用固定床反应器对催化剂进行评价.结果显示

PM催化剂具有较好的催化活性

此时的制备条件如下:反应温度为160?C

反应时间为2 h.对催化剂进行XRD

BET

EDS和SEM等表征

结果表明

PM催化剂具有微球形貌

提供丰富的孔道结构

较大的比表面积和更多的活性位点

改善了催化剂的催化性能.除此之外

反应中积碳可能是导致铋基催化剂失活的一个原因.

Abstract

In this work

Bi-based catalysts were prepared by one pot method(PM)and incipient wetness impregnation method(IM)and preparation conditions of the PM were researched.Catalytic activity of catalysts was evaluated using a fixed-bed reactor for acetylene hydrochlorination.The results displayed that the PM catalyst was prepared at 160?C for 2h possessed a superior catalytic performance compared to the IM catalyst.The characterizations of XRD

BET

EDS and SEM demonstrated that the PM catalyst was microspheres structure

which could provide richer channel structures

larger specific surface areas and more active centres

thus improving the catalytic performances of catalysts.In addition

carbon deposition in the reaction was a possible reason for Bi-based catalysts deactivation.

关键词

Keywords

references

Yoshioka T,Kameda T,Imai S,et al.Dechlorination of poly(vinyl chloride)using Na OH in ethylene glycol under atmospheric pressure[J].Polym Degrad Stab,2008,93(6):1138-1141.

Wei X,Shi H,Qian W,et al.Gas-phase catalytic hydrochlorination of acetylene in a two-stage fluidized-bed reactor[J].Ind Eng Chem Res,2008,48(1):128-133.

Conte M,Davies C J,Morgan D J,et al.Modifications of the metal and support during the deactivation and regeneration of Au/C catalysts for the hydrochlorination of acetylene[J].Catalysis Science&Technology,2013,3(1):128-134.

Zhang J L,Liu N,Li W,et al.Progress on cleaner production of vinyl chloride monomers over non-mercury catalysts[J].Frontiers of Chemical Science and Engineering,2011,5(4):514-520.

Hutchings G J,Grady D T.Hydrochlorination of acetylene:The effect of mercuric chloride concentration on catalyst life[J].Appl Catal,1985,17(1):155-160.

Zhang J L,He Z H,Li W,et al.Deactivation mechanism of Au Cl 3 catalyst in acetylene hydrochlorination reaction:a DFT study[J].Rsc Advances,2012,2(11):4814-4821.

Wang L,Wang F,Wang J D.Non-mercury catalytic acetylene hydrochlorination over a NH4F–urea-modified Pd/HY catalyst for vinyl chloride monomer production[J].New J Chem,2016,40(4):3019-3023.

Tiruvalam R C,Pritchard J C,Dimitratos N,et al.Aberration corrected analytical electron microscopy studies of sol-immobilized Au+Pd,Au{Pd}and Pd{Au}catalysts used for benzyl alcohol oxidation and hydrogen peroxide production[J].Faraday Discuss,2011,152:63-86.

Mitchenko S A,Krasnyakova T V,Mitchenko R S,et al.Acetylene catalytic hydrochlorination over powder catalyst prepared by pre-milling of K2Pt Cl4salt[J].J Mol Catal A Chem,2007,275(1):101-108.

Pu Y F,Zhang J L,Yu L,et al.Active ruthenium species in acetylene hydrochlorination[J].Appl Catal A,2014,488:28-36.

Zhang H Y,Li W,Jin Y H,et al.Ru-Co(III)-Cu(II)/SAC catalyst for acetylene hydrochlorination[J].Appl Catal,B,2016,189:56-64.

Zhou K,Si J K,Jia J C,et al.Reactivity enhancement of N-CNTs in green catalysis of C2H2hydrochlorination by a Cu catalyst[J].RSC Advances,2014,4(15):7766-7769.

Zhou K,Jia J C,Li X G,et al.Continuous vinyl chloride monomer production by acetylene hydrochlorination on Hg-free bismuth catalyst:From lab-scale catalyst characterization,catalytic evaluation to a pilot-scale trial by circulating regeneration in coupled fluidized beds[J].Fuel Process Technol,2013,108:12-18.

Wang F,Zhu P Y,Wang J D,Activated Carbon-Supported Bismuth Non-Mercuric Catalyst for Acetylene Hydrochlorination[J].Chemistry,2014,77(9):909-912.

李士伟.水蒸汽法再生乙炔氢氯化铋基无汞催化剂的研究[D].乌鲁木齐:新疆大学,2015

Peng H L,Chan C K,Meister S,et al.Shape evolution of layer-structured bismuth oxychloride nanostructures via low-temperature chemical vapor transport[J].Chem Mater,2008,21(2):247-252.

Yu J H,Wei B,Zhu L,et al.Flowerlike C-doped Bi OCl nanostructures:facile wet chemical fabrication and enhanced UV photocatalytic properties[J].Appl Surf Sci,2013,284:497-502.

Zhang X,Ai Z H,Jia F L,et al.Generalized one-pot synthesis,characterization,and photocatalytic activity of hierarchical Bi OX(X=Cl,Br,I)nanoplate microspheres[J].The Journal of Physical Chemistry C,2008,112(3):747-753.

Zhang X,Wang X B,Wang L W,et al.Synthesis of a highly efficient Bi OCl single-crystal nanodisk photocatalyst with exposing{001}facets[J].ACS Appl Mat Interfaces,2014,6(10):7766-7772.

Zhu L P,Liao G H,Bing N C,et al.Self-assembled 3D Bi OCl hierarchitectures:tunable synthesis and characterization[J].Cryst Eng Comm,2010,12(11):3791-3796.

Cui Z K,Mi L W,Zeng D W.Oriented attachment growth of Bi OCl nanosheets with exposed{110}facets and photocatalytic activity of the hierarchical nanostructures[J].J Alloys Compd,2013,549:70-76.

Li G B,Li W,Zhang J L.Strontium promoted activated carbon-supported gold catalysts for non-mercury catalytic acetylene hydrochlorination[J].Catalysis Science&Technology,2016,6(9):3230-3237.

Du Y F,Hu R S,Jia Y,et al.Cu Cl2promoted low-gold-content Au/C catalyst for acetylene hydrochlorination prepared by ultrasonic-assisted impregnation[J].J Ind Eng Chem,2016,37:32-41.

Ma W,Jacobs G,Graham U M,et al.Fischer–Tropsch Synthesis:Effect of K Loading on the Water–Gas Shift Reaction and Liquid Hydrocarbon Formation Rate over Precipitated Iron Catalysts[J].Top Catal,2014,57(6-9):561-571.

Wang L,Wang F,Wang J D.Catalytic properties of Pd/HY catalysts modified with NH4F for acetylene hydrochlorination[J].Catal Commun,2015,65:41-45.

Views

134

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

用于乙炔氢氯化的磷酸预处理活性炭负载Pd催化剂(英文)

Related Author

王丰

马磊

王吉德

Related Institution

石油天然气精细化工教育部和自治区重点实验室,新疆大学化学化工学院

⁰