介孔ZSM-5的制备、改性及其催化纤维二糖醇解的研究

薛来奇; 成康; 何伟

doi:10.13568/j.cnki.651094.2017.04.010

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介孔ZSM-5的制备、改性及其催化纤维二糖醇解的研究

更新时间：2026-01-21

- 介孔ZSM-5的制备、改性及其催化纤维二糖醇解的研究
- Journal of Xinjiang University (Natural Science Edition in Chinese and English) Vol. 34, Issue 4, Pages: 429-434(2017)
- 作者机构：
  
  1. 昌吉学院化学与应用化学系
  2. 厦门大学化学化工学院
- 作者简介：
- 基金信息：
- DOI：10.13568/j.cnki.651094.2017.04.010
  CLC： O643.32
- Published：2017
- 稿件说明：
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[1]薛来奇,成康,何伟.介孔ZSM-5的制备、改性及其催化纤维二糖醇解的研究[J],2017,34(04):429-434.
[1]薛来奇,成康,何伟.介孔ZSM-5的制备、改性及其催化纤维二糖醇解的研究[J],2017,34(04):429-434. DOI： 10.13568/j.cnki.651094.2017.04.010.

DOI：10.13568/j.cnki.651094.2017.04.010.

摘要

以脱硅法制得介孔分子筛HZSM–5为载体

通过浸渍负载四氯化锡(SnCl4·5H_2O)

再经1mol·L-1的硫酸处理后得到改性的SO42-/Sn–ZSM-5分子筛催化剂.采用XRD、氮气物理吸附、SEM和X射线能谱对合成的SO42-/Sn–ZSM-5催化剂进行了结构表征.结果发现

经负载和酸化后的催化剂仍然具有丰富的介孔结构和较大的比表面积(325.28 m2/g).将该催化剂用于催化纤维二糖的醇解

并探讨了反应温度、反应时间、催化剂用量等对总糖收率的影响.结果表明

当纤维二糖和甲醇用量分别为200 mg和20 mL

反应的最佳条件是:催化剂的用量为3.0 mg

反应温度为150?C

反应压力3 MPa

反应时间4 h

总糖的收率可达88%.上述表明SO2-4/Sn–ZSM-5为催化纤维二糖醇解的一类优良催化剂.

Abstract

Mesoporous molecular sieve H–ZSM–5 was synthesized

by desilication and then

loaded with stannic chloride(SnCl4·5H_2O) by the impregnation method.The precursor was further treated using sulfuric acid(1mol·L-1) to obtain the final catalysts

named

SO42-/Sn–ZSM–5.XRD

N2-adsorption SEM and the X-ray energy spectrum were used to the characterizethe structure properties of the as-prepared catalysts.The results showed that

SO42-/Sn–ZSM–5 catalyst still have abundant mesoporous structure and large specific surface area(325.28 m2/g) after the impregnation and acid treatment.The SO42-/Sn–ZSM–5 was used in the cellobiose alcoholysis reaction.The effects of temperature

reaction time and catalyst dosage on the total sugar yield were investigated.The experimental results showed that the total sugar yield was up to 88% under the optimal conditions where catalyst dosage 3.0 mg

temperature 150?C

pressure 3 MPa

and reaction time 4 h.The results indicate that the SO42-/Sn–ZSM–5 is an excellent catalyst for catalytic alcoholysis of cellobiose.

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references

Paivi M A,Arne H,Tapion S,et al.Recent progress in synthesis of fine and specialet chemicals from wood and other biomass by heterogeneous catalytic processes[J].Catalysis Reviews,2007,49:197-340.

Dhepe P L,Fukuoka A.Cellulose conversion under heterogeneous catalysis[J].Chem Sus Chem,2008,1(12):969-975.

Fleming K,Gray D G,Matthews S.Cellulose crystallites[J].Chemistry-A European Journal,2001,7(9):1831-1836.

Huber G W,Iborra S,Corma S.Synthesis of transportation fuel from biomass chemistry catalysts and engineering[J].Chemical Reviews,2006,106:4044-4098.

谭雪松,庄新姝,邓卫平,等.Ru/CNT催化纤维二糖加氢制备山梨醇的机理及动力学[J].化工学报,2010,(10):2579-2584.

徐蓉,奚永兰,张九花,等.利用纤维素水解液中的纤维二糖发酵制备丁二酸[J].化工进展,2013,(4):874-877.

张军营,杨小峰,侯宝林,等.纤维二糖与葡萄糖催化转化制备乙二醇[J].催化学报,2014,(11):1811-1817.

尹建军,邢伟静,李玉波,等.ZSM–5分子筛结晶度及晶粒大小的影响因素[J].分子催化,2012,26(2):162-168.

Laiqi Xue,Kang Cheng,Hongxi Zhang,et al.Mesoporous H–ZSM–5 as an ef?cient catalyst for conversions of cellulose and cellobiose into methyl glucosides in methanol.[J].Catalysis Today,2016,274:60-66.

陈艳艳,于如军,梁化,等.无晶种合成ZSM-5分子筛的研究[J].山东理工大学学报(自然科学版),2013,27(3):14-17.

Shan Xianglei,Cheng Zhenmin,Li Ying.Solvent Effects on Hydration of Cyclohexene over H–ZSM–5 Catalyst[J].J Chem Eng Data,2011,56(12):4310-4316.

李赫咺,项寿鹤,吴德明,等.ZSM–5沸石分子筛合成的研究[J].高等学校化学学报,1981,29(4):517-519.

房承宣,屈一新,王亚涛,等.预结晶法合成ZSM–5分子筛及催化环己烯水合制环己醇的研究[J].现代化工,2013,33(2):49-53.

Serrano D P,Garcia R A,Linares M,et al.Influence of the Calcination Treatment on the Catalytic Properties of Hierarchical ZSM–5[J].Catal Today,2012,179(1):91-101.

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