纤维素基荧光碳点的制备及应用研究进展

哈丽丹·买买提; 阿卜杜黑热木·阿瓦提; 古妮萨柯孜·伊斯拉木; 张云飞

doi:10.13568/j.cnki.651094.651316.2019.04.14.0001

您当前的位置：

首页 >

文章列表页 >

纤维素基荧光碳点的制备及应用研究进展

更新时间：2026-01-19

- 纤维素基荧光碳点的制备及应用研究进展
- Journal of Xinjiang University (Natural Science Edition in Chinese and English) Vol. 37, Issue 1, Pages: 29-35(2020)
- 作者机构：
  
  新疆大学化学与化工学院
- 作者简介：
- 基金信息：
- DOI：10.13568/j.cnki.651094.651316.2019.04.14.0001
  CLC： TQ127.11;O657.3
- Published：2020
- 稿件说明：
移动端阅览
[1]哈丽丹·买买提,阿卜杜黑热木·阿瓦提,古妮萨柯孜·伊斯拉木,等.纤维素基荧光碳点的制备及应用研究进展[J].新疆大学学报(自然科学版)(中英文),2020,37(01):29-35.
[1]哈丽丹·买买提,阿卜杜黑热木·阿瓦提,古妮萨柯孜·伊斯拉木,等.纤维素基荧光碳点的制备及应用研究进展[J].新疆大学学报(自然科学版)(中英文),2020,37(01):29-35. DOI： 10.13568/j.cnki.651094.651316.2019.04.14.0001.

DOI：10.13568/j.cnki.651094.651316.2019.04.14.0001.

摘要

纤维素基荧光碳点是以微晶纤维素、果皮、杂草、水果等多种纤维素资源为原料

通过水热合成、高温碳化、水解等方法制备的一种新型的荧光纳米粒子

它不仅具有类似传统量子点的光学性能

而且还具有良好的生物相容性、无毒性及易于表面功能化等特点

在离子监测、药物载体、细胞成像、以及光催化等领域具有巨大的应用潜力.本文就近年来纤维素基荧光碳点的研究进行了综述

着重介绍了其制备方法和应用的最新进展

并对其未来的发展方向进行了展望.

Abstract

Cellulose based ?uorescent carbon dots is a new type of ?uorescent nanoparticles synthesized by hydrothermal

or high-temperature carbonization

or hydrolysis et al. using microcrystalline cellulose

pericarp

weeds

fruit and other cellulose resources as raw materials. The cellulose based ?uorescent carbon dots not only has some special optical properties similar to the traditional quantum dots

but also has good biocompatibility

non-toxicity

and easy functionalization

therefore

it has demonstrated great potential in ion monitoring

drug delivery

cell imaging

and photocatalysis. In this paper

the recent research on cellulose based ?uorescent carbon dots have been reviewed

it focused on the latest progress of the preparation and application of cellulose based?uorescent carbon dots

and the future development direction was prospected.

关键词

Keywords

references

XU X, RAY R, GU Y, et al. Electrophoretic analysis and puri?cation of?uorescent single-walled carbon nanotube fragments[J].J Am Chem Soc, 2004, 126(40):12736-12737.

JIA X F, Li J, Wang E K. One-pot green synthesis of optically pH-sensitive carbon dots with upconversion luminescence[J].Nanoscale, 2012, 4(18):5572-5575.

KANG Z, TSANG C H A, WONG N B, et al. Silicon quantum dots:? a general photocatalyst for reduction, decomposition, and selective oxidation reactions[J]. J Am Chem Soc, 2007, 129(40):12090-12091.

YANG S T, WANG X, WANG H F, et al. Carbon dots as nontoxic and high-performance?uorescence imaging agents[J]. Journal of Physical Chemistry C, 2009, 113(42):18110-18114.

RAY S C, SAHA A, JANA N R, et al. Fluorescent carbon nanoparticles:synthesis, characterization, and bioimaging application[J].Journal of Physical Chemistry C, 2009, 113(43):18546-18551.

BAI W J, ZHENG H Z, LONG Y J. A carbon dots-based?uorescence turn-on method for DNA determination[J]. Anal Sci, 2011,27(3):243-243.

SUN Y P, WANG X, LU F S, et al. Doped carbon nanoparticles as a new platform for highly photoluminescent dots[J]. Journal of Physical Chemistry C, 2008, 112(47):18295-18298.

SHEN D, LONG Y, WANG J, et al. Tuning the?uorescence performance of carbon dots with a reduction pathway[J]. Nanoscale,2019, 11(13):5998-6003.

YANG S T, CAO L, LUO P G, et al. Carbon dots for optical imaging in vivo[J]. J Am Chem Soc, 2009, 131(32):11308-11309.

LI H L, ZHANG Y W, WANG L, et al. Nucleic acid detection using carbon nanoparticles as a?uorescent sensing platform[J].Chem Commun, 2011, 47(3):961-963.

LIU S, TIAN J, WANG L, et al. Hydrothermal treatment of grass:a low-cost, green route to nitrogen-doped, carbon-rich,photoluminescent polymer nanodots as an effective?uorescent sensing platform for label-free detection of Cu(II)ions[J]. Adv Mater, 2012, 24(15):2037-2041.

GUO Y, WANG X, SUN R. Cellulose-based self-assembled nanoparticles for antitumor drug delivery[J]. J Controlled Release,2013, 172(1):e85.

NISHIKIORI H, OHTA T, UESUGI Y, et al. In?uence of adding carbon nanotubes on photoelectric conversion properties of dye-doped titania gel[J]. Res Chem Intermed, 2012, 38(8):1857-1869.

LI H, HE X, KANG Z, et al. Water-soluble?uorescent carbon quantum dots and photocatalyst design[J]. Angew Chem Int Ed,2010, 49(26):4430-4434.

HU S L, NIU K Y, SUN J, et al. One-step synthesis of?uorescent carbon nanoparticles by laser irradiation[J]. J Mater Chem,2009, 19(4):484-488.

CHAI L, ZHOU J, FENG H, et al. Functionalized carbon quantum dots with dopamine for tyrosinase activity monitoring and inhibitor screening:in vitro and intracellular investigation[J]. ACS Applied Materials&Interfaces, 2015, 7(42):23564-23574.

LI M Y, YU C, HU C, et al. Solvothermal conversion of coal into nitrogen-doped carbon dots with singlet oxygen generation and high quantum yield[J]. Chem Eng J, 2017, 320:570-575.

LI H R, LI R, DENG A M. A solvothermal method to synthesize?uorescent carbon nanoparticles and application to photocatalysis and electrocatalysis[J]. Luminescence, 2015, 30(6):740-744.

LI F, TIAN F, LIU C, et al. One-step synthesis of nanohybrid carbon dots and TiO2composites with enhanced ultraviolet light active photocatalysis[J]. RSC Advances, 2015, 5(11):8389-8396.

LI H, ZHU Y, CAO H, et al. Preparation and characterization of photocatalytic carbon dots-sensitized electrospun titania nanostructured?bers[J]. Mater Res Bull, 2013, 48(2):232-237.

ZHANG H C, HUANG H, MING H, et al. Carbon quantum dots/Ag3PO4complex photocatalysts with enhanced photocatalytic activity and stability under visible light[J]. J Mater Chem, 2012, 22(21):10501-10506.

LI H T, LIU R H, LIU Y, et al. Carbon quantum dots/Cu2O composites with protruding nanostructures and their highly efficient(near)infrared photocatalytic behavior[J]. J Mater Chem, 2012, 22(34):17470-17475.

DE B, VOIT B, KARAK N. Carbon dot reduced Cu2O nanohybrid/hyperbranched epoxy nanocomposite:mechanical, thermal and photocatalytic activity[J]. RSC Advances, 2014, 4(102):58453-58459.

WANG J, GAO M, HO G W. Bidentate-complex-derived TiO2/carbon dot photocatalysts:in situ synthesis, versatile heterostructures, and enhanced H2evolution[J]. Journal of Materials Chemistry A, 2014, 2(16):5703-5709.

YANG Y, CUI J, ZHENG M, et al. One-step synthesis of amino-functionalized?uorescent carbon nanoparticles by hydrothermal carbonization of chitosan[J]. Chem Commun(Camb), 2012, 48(3):380-383.

CHOWDHURY D, GOGOI N, MAJUMDAR G. Fluorescent carbon dots obtained from chitosan gel[J]. RSC Advances, 2012,2(32):12156-12159.

SHEN P, GAO J, CONG J, et al. Synthesis of cellulose-based carbon dots for bioimaging[J]. Chemistry Select, 2016, 1(7):1314-1317.

LI W, ZHANG H, ZHENG Y, et al. Multifunctional carbon dots for highly luminescent orange-emissive cellulose based composite phosphor construction and plant tissue imaging[J]. Nanoscale, 2017, 9(35):12976-12983.

LIMA M D S M, BORSALI R. Rodlike cellulose microcrystals:structure, properties, and applications[J]. Macromol Rapid Commun, 2004, 25(7):771-787.

ZHANG X, WANG H, MA C, et al. Seeking value from biomass materials:preparation of coffee bean shell-derived?uorescent carbon dots via molecular aggregation for antioxidation and bioimaging applications[J]. Materials Chemistry Frontiers, 2018, 2(7):1269-1275.

LU W, QIN X, LIU S, et al. Economical, green synthesis of?uorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(II)ions[J]. Analytical Chemistry, 2012, 84(12):5351-5357.

KRYSMANN M J, KELARAKIS A, GIANNELIS E P. Photoluminescent carbogenic nanoparticles directly derived from crude biomass[J]. Green Chemistry, 2012, 14(11):3141-3145.

SAXENA M, SARKAR S. Synthesis of carbogenic nanosphere from peanut skin[J]. Diamond&Related Materials, 2012, 24(4):11-14.

ZHOU J, SHENG Z, HAN H, et al. Facile synthesis of?uorescent carbon dots using watermelon peel as a carbon source[J].Materials Letters, 2012, 66(1):222-224.

PENG H, TRAVASSEJDIC J. Simple aqueous solution route to luminescent carbogenic dots from carbohydrates[J]. Chemistry of Materials, 2009, 21(23):5563-5565.

ZHANG Y F, Halidan Maimaiti H, ZHANG B. Preparation of cellulose-based?uorescent carbon nanoparticles and their application in trace detection of Pb(ii)[J]. RSC Advances, 2017, 7(5):2842-2850.

李育飞,白绘宇,王玮,等.纳米晶纤维素改性及其功能性材料的研究进展[J].纤维素科学与技术, 2016, 24(1):66-74.LI Y F, BAI H Y, WANG W, et al. Progress in modi?cation of cellulose nanocrystals and the application in functional materials[J].Journal of Cellulose Science and Technology, 2016, 24(1):66-74.(in Chinese)

LV P, YAO Y, LI D, et al. Self-assembly of nitrogen-doped carbon dots anchored on bacterial cellulose and their application in iron ion detection[J]. Carbohydr Polym, 2017, 172:93-101.

陈文新,阳运华,刘应亮,等.基于生物质甘蔗渣的荧光碳量子点制备[J].暨南大学学报(自然科学与医学版), 2015, 36(1):1-6.CHEN W X, YANG Y H, LIU Y L, et al. Facile synthesis of?uorescent carbon nanodots derived from biomass bagasse by hydrothermal treatment[J]. Journal of Jinan University(Natural Science and Medicine Edition), 2015, 36(1):1-6.(in Chinese)

KIERZEK K, PIOTROWSKA A, MACHNIKOWSKI J. Cellulose-based carbon—a potential anode material for lithium-ion battery[J]. J Phys Chem Solids, 2015, 86:215-222.

杜全周.新型酸性离子液体水解纤维素制备荧光碳点的研究[J].新乡学院学报, 2015, 32(12):24-27.DU Q Z. Research on the preparation for carbon dots with cellulose catalyzed by a novel acid ionic liquid[J]. Journal of Xinxiang University, 2015, 32(12):24-27.(in Chinese)

ZHOU K, DU Q, BAI G, et al. Hydrolysis of cellulose catalyzed by novel acidic ionic liquids[J]. Carbohydr Polym, 2015, 115:49-53.

WANG C, WANG C, XU P, et al. Synthesis of cellulose-derived carbon dots using acidic ionic liquid as a catalyst and its application for detection of Hg2+[J]. Journal of Materials Science, 2016, 51(2):861-867.

李敏,徐梦,程朝歌,等.氨基功能化荧光碳量子点的制备及对铜离子的检测[J].材料导报, 2017, 31(A02):157-160.LI M, XU M, CHENG C G, et al. Preparation of amine-functionalized?uorescent carbon quantum dots and its application for cooper ions detection[J]. Materials Reports, 2017, 31(A02):157-160.(in Chinese)

YANG G, WAN X, SU Y, et al. Acidophilic S-doped carbon quantum dots derived from cellulose?bers and their?uorescence sensing performance for metal ions in an extremely strong acid environment[J]. Journal of Materials Chemistry A, 2016, 4(33):12841-12849.

Cayuela A, Soriano M L, Valc′arcel M. Photoluminescent carbon dot sensor for carboxylated multiwalled carbon nanotube detection in river water[J]. Sensors and Actuators B:Chemical, 2015, 207:596-601.

WU P, LI W, WU Q, et al. Hydrothermal synthesis of nitrogen-doped carbon quantum dots from microcrystalline cellulose for the detection of Fe3+ions in an acidic environment[J]. RSC Advances, 2017, 7(70):44144-44153.

RAI S, SINGH B K, BHARTIYA P, et al. Lignin derived reduced?uorescence carbon dots with theranostic approaches:Nanodrug-carrier and bioimaging[J]. J Lumin, 2017, 190:492-503.

GUO Y, WANG X, SUN R. Cellulose-based self-assembled nanoparticles for antitumor drug delivery[J]. Journal of Controlled Release, 2013, 172(1):85-86.

ZHAO J, WEI Z, FENG X, et al. Luminescent and transparent nanopaper based on rare-earth up-converting nanoparticle grafted nano?brillated cellulose derived from garlic skin[J]. ACS Applied Materials&Interfaces, 2014, 6(17):14945-14951.

GONG C H, WANG X X, LIU H J, et al. Facile in situ synthesis of nickel/cellulose nanocomposites:mechanisms, properties and perspectives[J]. Cellulose, 2014, 21(6):4359-4368.

ZHANG J, LIU W, WANG P, et al. Photocatalytic behavior of cellulose-based paper with TiO2loaded on carbon?bers[J]. Journal of Environmental Chemical Engineering, 2013, 1(3):175-182.

WANG J, NG Y H, LIM Y F, et al. Vegetable-extracted carbon dots and their nanocomposites for enhanced photocatalytic H2production[J]. RSC Advances, 2014, 4(83):44117-44123.

TYAGI A, TRIPATHI K M, SINGH N, et al. Green synthesis of carbon quantum dots from lemon peel waste:applications in sensing and photocatalysis[J]. RSC Advances, 2016, 6(76):72423-72432.

Halidan Maimaiti, Abuduheiremu Awati, Gunisakezi Yisilamu, et al. Synthesis and visible-light photocatalytic CO2/H2O reduction to methyl formate of TiO2nanoparticles coated by aminated cellulose[J]. Appl Surf Sci, 2019, 466:535-544.

SHEN P, GAO J, CONG J, et al. Synthesis of cellulose-based carbon dots for bioimaging[J]. Chemistryselect, 2016, 1(7):1314-1317.

WANG Y, WANG S, YANG X. Carbon dots derived from carboxymethylcellulose for sensing both isoniazid and H2O2[J]. New Journal of Chemistry, 2018, 42(6):4109-4113

ROY P, CHEN P C, PERIAMY A P, et al. Photoluminescent carbon nanodots:synthesis, physicochemical properties and analytical applications[J]. Materials Today, 2015, 18(8):447-458.

Views

865

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

浅谈三相异步电动机软起动器的性能及应用

纳米技术及其在纺织上的应用

农业生态环境适应性近似理论及其应用(英文)

2-噻吩甲醛缩氨基硫脲衍生物蓝光材料

在缓冲液中制备Mg_6Al₂(OH)₁₃-SO₄-CO₃-Br·5.5H_2O及其结构分析

Related Author

白丽克孜·尤努斯

古丽巴哈尔·托呼提

夏涛

徐建华

Robert W.McColl

胡锡建

盛蕊

车圆圆

Related Institution

新疆大学机械工程学院,新疆大学机械工程学院新疆乌鲁木齐830008

新疆大学纺织工程系

兰州大学地理系,美国堪萨斯大学地理系,新疆大学数学系,

新疆大学应用化学研究所能源材料化学教育部重点实验室

岭南师范学院化学化工学院

⁰