铁氮掺杂生物质/聚苯胺衍碳氧还原催化剂研究

姚智子; 冯欢欢; 董森; 李源; 马俊红

doi:10.13568/j.cnki.651094.651316.2021.03.25.0001

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铁氮掺杂生物质/聚苯胺衍碳氧还原催化剂研究

更新时间：2026-01-21

- 铁氮掺杂生物质/聚苯胺衍碳氧还原催化剂研究
- Journal of Xinjiang University (Natural Science Edition in Chinese and English) Vol. 39, Issue 3, Pages: 314-322(2022)
- 作者机构：
  
  新疆大学化工学院
- 作者简介：
- 基金信息：
- DOI：10.13568/j.cnki.651094.651316.2021.03.25.0001
  CLC： TM911.4;O643.36
- Published：2022
- 稿件说明：
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[1]姚智子,冯欢欢,董森,等.铁氮掺杂生物质/聚苯胺衍碳氧还原催化剂研究[J].新疆大学学报(自然科学版)(中英文),2022,39(03):314-322.
[1]姚智子,冯欢欢,董森,等.铁氮掺杂生物质/聚苯胺衍碳氧还原催化剂研究[J].新疆大学学报(自然科学版)(中英文),2022,39(03):314-322. DOI： 10.13568/j.cnki.651094.651316.2021.03.25.0001.

DOI：10.13568/j.cnki.651094.651316.2021.03.25.0001.

摘要

研究高性价比的非贵金属氧还原反应(ORR)催化剂对清洁能源的大规模开发有重要意义，本研究以聚苯胺(PANI)和生物质废弃物豆渣共同作为碳/氮前驱体材料，g-C_3N4为辅助氮源和致孔剂，氯化铁作为氧化剂和铁源制备得到了一种具有多孔结构的铁氮共掺杂生物质/聚苯胺衍碳材料(Fe-N-CB/CPANI)．系统考察了氯化铁用量对催化剂样品结构及ORR催化性能的影响，优化后的催化剂样品Fe-N-CB/CPANI-2对ORR具有良好的催化活性，其起始电势相对商业催化剂Pt/C正移50 m V，抗甲醇性能和稳定性明显优于Pt/C.

Abstract

The study of cost-effective non-precious metal oxygen reduction reaction(ORR) catalysts is of great significance to the large-scale development of clean energy. In this work

iron and nitrogen co-doped biomass/polyaniline derived carbon materials(Fe-N-CB/CPANI) with porous structure were fabricated by using both polyaniline(PANI)and biomass waste bean dregs as carbon/nitrogen precursors

g-C_3N_4as both the additional nitrogen source and porogen

ferric chloride as an oxidant and iron source. The effect of ferric chloride dosage on the structure and ORR performance of the prepared catalysts was systematically investigated

the optimized Fe-N-CB/CPANI-2 catalyst exhibits decent ORR behavior with initial potential 50 m V positively shifted in comparison to commercial Pt/C

and the methanol resistance and ORR stability of Fe-N-CB/CPANI-2 are even better than Pt/C.

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references

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