用于中间相沥青制备的两种催化裂化油浆组成分析

张彪; 董森; 唐亚昆; 刘浪; 刘宏博; 李杨俊迪; 何平; 刘景梅; 马凤云

doi:10.13568/j.cnki.651094.651316.2023.03.09.0001

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用于中间相沥青制备的两种催化裂化油浆组成分析

更新时间：2026-01-21

- 用于中间相沥青制备的两种催化裂化油浆组成分析
- Journal of Xinjiang University (Natural Science Edition in Chinese and English) Vol. 40, Issue 6, Pages: 704-708(2023)
- 作者机构：
  
  1. 新疆大学化学学院省部共建碳基能源资源化学与利用国家重点实验室
  2. 克拉玛依市先进能源技术创新有限公司
- 作者简介：
- 基金信息：
- DOI：10.13568/j.cnki.651094.651316.2023.03.09.0001
  CLC： TE624.41
- Published：2023
- 稿件说明：
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[1]张彪,董森,唐亚昆,等.用于中间相沥青制备的两种催化裂化油浆组成分析[J].新疆大学学报(自然科学版)(中英文),2023,40(06):704-708+723.
[1]张彪,董森,唐亚昆,等.用于中间相沥青制备的两种催化裂化油浆组成分析[J].新疆大学学报(自然科学版)(中英文),2023,40(06):704-708+723. DOI： 10.13568/j.cnki.651094.651316.2023.03.09.0001.

DOI：10.13568/j.cnki.651094.651316.2023.03.09.0001.

摘要

中间相沥青作为制备高性能碳材料的重要前驱体，研究影响中间相沥青结构的因素(原料组成和制备工艺)对推动碳材料发展具有重要意义．以新疆两种催化裂化油浆为原料，经凝胶渗透色谱(GPC)、核磁共振氢谱(~1H-NMR)、元素分析、气相色谱-质谱联用(GC-MS)等系统表征，明晰了其组成与结构特点．针对油浆高饱和分特性(>47%)，一改传统原料溶剂精制策略，采用先热解优化原料组成，再热缩聚两步法制得软化点为290℃的广域型中间相沥青．

Abstract

It is of great significance to promote the development of carbon materials by studying the factors(composition of raw materials and preparation process) affecting the structure of mesophase asphalt as an important precursor for the preparation of high-performance carbon materials. Here

two fluid catalytic cracking slurries from Xinjiang were characterized by Gel Permeable Chromatography(GPC)

~1H Nuclear Magnetic Resonance(~1H-NMR)

elemental analysis and Gas Chromatography-Mass Spectrometry(GC-MS) to clarify their composition and structural characteristics. In response to the high saturated fraction characteristic of oil slurry(>47%)

a two-step method of optimizing the composition of raw materials by pyrolysis followed by thermal poly condensation was used to produce a wide-area mesophase asphalt with a softening point of 290 ℃ instead of the traditional solvent refining strategy.

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references

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